[μ-Butane-1,4-diylbis(diphenylphosphane)-κ2 P:P′]bis{[butane-1,4-diylbis(diphenylphosphane)-κ2 P,P′]copper(I)} bis(hexafluoridophosphate) diethyl ether disolvate
نویسندگان
چکیده
In the centrosymmetric dinuclear copper(I) complex cation of the title compound, [Cu2(C28H28P2)3](PF6)2·2C4H10O, the Cu(I) atom is bonded to three P atoms of two butane-1,4-diylbis(di-phenyl-phosphane) (dppb) ligands with a triangular coordination geometry. One of these P atoms belongs to a bridging dppb ligand [Cu-P = 2.2381 (5) Å] and two belong to a chelating dppb ligand [Cu-P = 2.2450 (6) and 2.2628 (5) Å]. The bridging dppb ligand lies on an inversion centre. In the crystal, the cation and the PF6 (-) anion are linked by C-H⋯F inter-actions, forming a tape along [110]. The cation and the diethyl ether solvent mol-ecule are also linked by a C-H⋯O inter-action.
منابع مشابه
Crystal structure of bis[μ-1,4-bis(diphenylphosphanyl)butane-κ2 P:P′]bis[(3,4,7,8-tetramethyl-1,10-phenanthroline-κ2 N,N′)copper(I)] bis(hexafluoridophosphate) dichloromethane disolvate
The dication of the title compound, [Cu2(C28H28P2)2(C16H16N2)2](PF6)2·2CH2Cl2, has crystallographically imposed inversion symmetry. The copper(I) cation is coordinated in a distorted tetra-hedral geometry by two N atoms of a chelating 3,4,7,8-tetra-methyl-1,10-phenanthroline ligand and two P atoms of two bridging 1,4-bis-(di-phenyl-phosphan-yl)butane ligands, forming a 14-membered ring. An intr...
متن کامل[μ-N,N′-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-κ2 P:P′]bis[(2,2′-bipyridine-κ2 N,N′)silver(I)] bis(perchlorate) acetone disolvate
The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.
متن کاملPoly[[tris[μ-2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole)-κ2 N 4:N 4′]copper(II)] bis(perchlorate)]
In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole) ligands in a slightly distorted octa-hedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thia-diazole ligands, which are situated about inversion...
متن کاملCrystal structure of poly[[μ-1,1′-(butane-1,4-diyl)bis(1H-benzimidazole)-κ2 N 3:N 3′]{μ-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4 O,O′:O′′,O′′′}cobalt(II)]
In the title compound, [Co(C20H12O6)(C18H18N4)] n , the Co(II) atom, located on a twofold rotation axis, is hexa-coordinated to four O from two bis-bidentate 4,4'-[phenyl-enebis(-oxy)]dibenzoate (L) ligands and two N atoms from two 1,1'-(butane-1,4-di-yl)bis-(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N2O4 coordination environment. Polymeric zigzag chains along [102] a...
متن کامل(2Z,2′Z)-Diethyl 3,3′-[butane-1,4-diylbis(azanediyl)]bis(but-2-enoate)
The whole mol-ecule of the title β-enamino-ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C-C bond of the 1,4-diamino-butane segment. There are two intra-molecular N-H⋯O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756 (17) Å]. The mol-ecule is S-shaped with the p...
متن کامل